Pogba, who helped hosts France reach the Euro 2016 final, has won the Serie A title in each of his four seasons at Juventus.
He is Mourinho’s fourth signing at United, after 1xbet Ivory Coast defender Eric Bailly, former Sweden striker Zlatan Ibrahimovic and Armenia forward Henrikh Mkhitaryan.
It will be the first time in 20 years an English club has paid a world-record fee – Alan Shearer’s move to Newcastle United from Blackburn Rovers for £15m was the last.
Pogba joined United from French club Le Havre in 2009 as a 16-year-old, but made just a handful of appearances before his contract expired in July 2012.
He has made 178 appearances for Juventus, scoring 34 goals, and helped the club reach the 2015 Champions League final. The Serie A side had offered him a new contract, while Real Madrid were also interested in signing him.
Pogba said his mum has told him he would return to Old Trafford and that it was his “destiny”.
Speaking to MUTV he added: “I just 1xbet came back to Carrington. It was like I’d just come back home. I just went for a holiday.”
In a series of messages to Juventus supporters on social media, Pogba said: “Goodbye means nothing, it is the time we spent together that matters. I will bring with me a piece of you and leave you a little piece of me.”
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